An EPR study into the effect of annealing on both the Mn2+ and free radical signal in lentil


POLAT M., KORKMAZ M.

INTERNATIONAL JOURNAL OF FOOD SCIENCE AND TECHNOLOGY, cilt.36, sa.3, ss.313-320, 2001 (SCI-Expanded) identifier identifier

Özet

The results of an EPR investigation on dry lentil (macrosperma) are reported in the present work. The EPR spectrum of lentil is composed of an equally spaced sextet and a single weak resonance line appearing at g=2.0050. Whole intact individual and decorticated seeds and testa were studied separately; however, ground lentil was used throughout the work to avoid any possible problems arising from the microwave cavity filling factor. Although intact and decorticated seeds were found to exhibit both Mn2+ and radical signals, the testa exhibited only the radical signal. An increase and decrease of Mn2+ and radical signals were observed, respectively, below room temperature. Above room temperature, they both decreased and these decreases were irreversible. The kinetics of these decreases were studied in detail over a temperature range of room-423 K by annealing samples at different temperatures for various times.