Akademik Veri Yönetim Sistemi
JAOCS, Journal of the American Oil Chemists' Society, cilt.100, sa.10, ss.815-827, 2023 (SCI-Expanded)
The extraction of butter from cocoa seeds involves various processing steps that weaken the lipid-storing cell walls of cocoa cotyledons. Roasting is particularly critical, making cocoa nibs porous and brittle. In this study, the degree of disruption of the microstructure of cocoa nibs, and the quality and aroma profile of cocoa butter, were evaluated using two roasting techniques, forced convective oven, and fluidized bed. Fluidized bed roasting, recognized for its energy efficiency and low-carbon footprint, was 12 times faster than oven roasting. This technique allowed a rapid release of steam when parenchyma cell walls were still in a glassy state, while oven roasting caused gradual physical modification allowing the cell wall to become more elastic. Consequently, small pores expanded and coalesced to produce larger pores. X-ray tomographic analysis showed a total porosity in unroasted cocoa nibs of 8.5 ± 2.0% (vol/vol), which was doubled upon oven roasting and triplicated upon fluidized bed roasting. The higher porosity in fluidized-bed-roasted nibs was reflected in the lowest densities and highest cocoa butter yield. Cocoa butter obtained from fluidized-bed roasted cocoa showed a higher presence of pyrazines and 3-methylbutanal, and a lower concentration of hydroperoxides, thus enhancing the chocolate flavor and quality. In this paper, we proved that the pore structure of cocoa nibs is a key quality descriptor of roasting processing, and we concluded by quality considerations that fluidized bed roasting technique should be preferred for cocoa nibs roasting over conventional roasting.