Structure and characterization of N-(2-hydroxy-1-naphthylidene)threonine

Ozcan Y., Ide S., Sakiyan I., Logoglu E.

JOURNAL OF MOLECULAR STRUCTURE, vol.658, no.3, pp.207-213, 2003 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 658 Issue: 3
  • Publication Date: 2003
  • Doi Number: 10.1016/s0022-2860(03)00455-1
  • Journal Name: JOURNAL OF MOLECULAR STRUCTURE
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.207-213
  • Hacettepe University Affiliated: Yes

Abstract

Threonine Schiff base derived 2-hydroxy-1-naphthaldehyde and threonine has been isolated and investigated. The stoichiometry of this compound was derived from the results of elemental analyses, IR, H-1-NMR and UV spectroscopic techniques. X-ray diffraction method was also used to obtain the single-crystal structure. The compound crystallizes in the space group P2(1) with cell dimensions a = 5.109(2), b = 11.334(2), c = 11.155(3) Angstrom and beta = 91(3)degrees with Z = 2. The molecule has phenol-imine tautomeric form in the crystal structure. Some of bond lengths and angles found in the molecular structure are distorted due to pi-electron delocalization and steric effect of naphthylidene and threonine groups. (C) 2003 Elsevier B.V. All rights reserved.