Spectral and structural studies of Ni(II) and Zn(II) complexes of N-trans-cinnamylidene-2-mercaptoaniline


Ancin N., Ide S., Oztas S., Tuzun M., Sahin E.

JOURNAL OF MOLECULAR STRUCTURE, cilt.608, sa.1, ss.89-93, 2002 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 608 Sayı: 1
  • Basım Tarihi: 2002
  • Doi Numarası: 10.1016/s0022-2860(01)00936-x
  • Dergi Adı: JOURNAL OF MOLECULAR STRUCTURE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.89-93
  • Hacettepe Üniversitesi Adresli: Evet

Özet

Ni(II) and Zn(II) complexes of the bidentate thiol ligand N-traps-cinnamylidene-2-mercaptoaniline which is obtained from traps-cinnamaldehyde and 2-mercaptoaniline were prepared and characterized by their IR absorption spectra, X-ray powder diffraction measurements, elemental analysis and H-1-NMR spectra. On the other hand, energy minimization studies of the molecules were carried out to obtain the most probable three-dimensional molecular conformations. The comparative H-1-NMR, IR, X-ray powder diffraction and energy minimization studies have shown that metal atoms are connected to the N and S atoms of Schiff bases and the complex have cis type fashion. (C) 2002 Elsevier Science B.V. All rights reserved.