Triterpene saponins from Calendula arvensis


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Kirmizibekmez H., Bassarello C., Piacente S., Pizza C., Calis I.

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, cilt.61, sa.9, ss.1170-1173, 2006 (SCI-Expanded) identifier identifier

Özet

From the aerial parts of Calendula arvensis a new triterpene saponin arvensoside C (1) was isolated together with four known triterpene saponins. The aglycon moieties had the oleanane skeleton for all of them. Three known flavonol glycosides, isorhamnetin 3-O-beta-D-glucopyranoside, quercetin 3-O-beta-D-glucopyranoside and quercetin 3-O-beta-D-galactopyranoside were also obtained and characterized. Their structures were elucidated by 1D and 2D NMR experiments including 1D-TOCSY, DQF-COSY, HOHAHA, HSQC and HMBC spectroscopy as well as HRESIMS analysis.