THE CRYSTAL-STRUCTURE OF A N-(2-THIOPHENYL)-SALICYLALDIMINO-PIPERIDINO NICKEL(II) COMPLEX

KABAK M., ELERMAN Y., OZBEY S., ATAKOL O.

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, vol.25, no.5, pp.259-262, 1995 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 25 Issue: 5
  • Publication Date: 1995
  • Doi Number: 10.1007/bf01665180
  • Journal Name: JOURNAL OF CHEMICAL CRYSTALLOGRAPHY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.259-262
  • Hacettepe University Affiliated: Yes

Abstract

The crystal and molecular structure of the title complex, C18H19N2OSNi, has been determined by direct methods. The compound crystallizes in monoclinic crystal system with a = 11.968(1), b = 12.182(1), c = 12.399(1) Angstrom, beta = 115.23(1)degrees, space group P2(1)/n. Nickel is in a slightly distorted square-planar environment of two nitrogens [1.881(2) and 1.952(2) Angstrom] and one oxygen [1.856(3) Angstrom] and one sulphur [2.138(2) Angstrom] atom. Ni is 0.005 Angstrom out of the plane of its ligands.