Bis(4-ethylbenzoato-kappa O)bis(nicotinamide-kappa N-1)zinc(II)

Necefoglu, Hacali; Ozbek, Fureya; Aktas, Vedat; Tercan, Baris; HÖKELEK, TUNCER

doi:10.1107/s1600536811006830

Bis(4-ethylbenzoato-kappa O)bis(nicotinamide-kappa N-1)zinc(II)

Atıf İçin Kopyala

Necefoglu H., Ozbek F. E., Aktas V., Tercan B., HÖKELEK T.

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, cilt.67, 2011 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 67
Basım Tarihi: 2011
Doi Numarası: 10.1107/s1600536811006830
Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Hacettepe Üniversitesi Adresli: Evet

Özet

The title Zn II complex, [Zn(C9H9O2)(2)(C6H6N2O)(2)], contains two 4-ethylbenzoate and two nicotinamide monodentate ligands, leading to a distorted tetrahedral coordination of the Zn-II ion. The dihedral angles between the carboxylate groups and the adjacent benzene rings are 10.33 (13) and 2.38 (11)degrees, while opposite pyridine and benzene rings are oriented at dihedral angles of 68.46 (5) and 81.09 (6)degrees. In the crystal, intermolecular N-H center dot center dot center dot O hydrogen bonds link the molecules, forming a three-dimensional network. C-H center dot center dot center dot O interactions also occur as well as two weak C-H center dot center dot center dot pi interactions involving the benzene rings.