Direct Transformation of Primary Nitro Compounds into Nitriles with Sodium Dithionite


Temelli B., ÜNALEROĞLU C.

SYNTHESIS-STUTTGART, vol.46, no.10, pp.1407-1412, 2014 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 46 Issue: 10
  • Publication Date: 2014
  • Doi Number: 10.1055/s-0033-1370874
  • Journal Name: SYNTHESIS-STUTTGART
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.1407-1412
  • Keywords: nitriles, sulfur, nitro compounds, synthetic methods, radicals, PALLADIUM-CATALYZED CYANATION, DIRECT OXIDATIVE CONVERSION, HETEROGENEOUS CATALYST, SYNTHETIC METHODS, PRIMARY AMIDES, ARYL HALIDES, ALDEHYDES, ALDOXIMES, CONVENIENT, REDUCTION
  • Hacettepe University Affiliated: Yes

Abstract

A new and practical direct transformation of primary nitro compounds into nitriles with sodium dithionite is described. The reaction is simple, convenient and eliminates the use of expensive and moisture-sensitive reagents.