Phosphorus-nitrogen compounds: Novel spirocyclic phosphazene derivatives. Structure of 3,3 ''-propane-1,3-diylbis[4 ',4 ',6 ',6 '-tetrachloro-3,4-dihydrospiro[1,3,2-benzoxazaphosphorine-2,2 'lambda(5)-[4 lambda(5),6 lambda(5)][1,3,5,2,4,6]triazatriphosphorine]]


BILGE S., NATSAGDORJ A., DEMIRIZ S., CAYLAK N., KILIC Z., Hokelek T.

HELVETICA CHIMICA ACTA, cilt.87, sa.8, ss.2088-2099, 2004 (SCI İndekslerine Giren Dergi) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 87 Konu: 8
  • Basım Tarihi: 2004
  • Doi Numarası: 10.1002/hlca.200490188
  • Dergi Adı: HELVETICA CHIMICA ACTA
  • Sayfa Sayıları: ss.2088-2099

Özet

The reactions of N2O2-donor-type aminopodands 1-3 with trimer N3P3Cl6 led to the novel spirocyclic phosphazene derivatives 4-10 (Scheme). Compounds 4-7 and 8-10 are the first examples of the substituted spiro-ansa-spiro and spiro-bino-spiro phosphazene derivatives, respectively. The pyrrolidinyl-substituted phosphazene derivatives 7 and 10 were synthesized from 5 and 9, respectively, with an excess of pyrrolidine. ne reaction of aminopodand 3 (R=(CH2)(4)) with N3P3Cl6 in dry THF afforded only spiro-ansa-spiro phosphazene 6. The molecular structure of compound 9 was determined by X-ray diffraction: it shows the novel spiro-bino-spiro phosphazene architecture.