Diaquabis(4-chlorobenzoato-kappa O)bis(N,N-diethylnicotinamide-kappa N-1)manganese(II)


HÖKELEK T. , Caylak N., Necefoglu H.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, vol.64, 2008 (Journal Indexed in SCI) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: 64
  • Publication Date: 2008
  • Doi Number: 10.1107/s1600536808005540
  • Title of Journal : ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS

Abstract

The title compound, [Mn(C7H4ClO2)(2)(C10H14N2O)(2)(H2O)(2)], is a monomeric complex with the Mn-II atom lying on an inversion center. It contains two 4-chlorobenzoate and two diethylnicotinamide ligands and two water molecules, all of which are monodentate. The four O atoms in the equatorial plane around the Mn atom form a slightly distorted square-planar arrangement, while the distorted octahedral geometry is completed by two N atoms in the axial positions. In the crystal structure, O-H center dot center dot center dot O hydrogen bonds link the molecules into an infinite chain.