Triterpene saponins from <i>Scabiosa rotata</i>


Baykal T., Panayir T., Tasdemir D., Sticher O., Calis I.

PHYTOCHEMISTRY, no.5, pp.867-873, 1998 (SCI-Expanded) identifier identifier identifier

  • Publication Type: Article / Article
  • Publication Date: 1998
  • Doi Number: 10.1016/s0031-9422(97)00982-5
  • Journal Name: PHYTOCHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Index Chemicus (IC)
  • Page Numbers: pp.867-873
  • Hacettepe University Affiliated: Yes

Abstract

Four new allose-containing triterpenoid saponosides, scabriosides A, B, C and D were isolated from the roots of Scabiosa rotata. Their structures were established as 3-O-beta-D-xylopyranosyl-28-O-[beta-D-allopyranosyl(1 --> 6)-beta-D-glucopyranosyl]-pomolic acid, 3-O-[alpha-L-rhamnopyranosyl(1 --> 2)-beta-D-xylopyranosyl]-28-O-[beta-D-allopyranosyl(1 --> 6)-beta-D-glucopyranosyl]-pomolic acid, 3-O-[a-L-rhamnopyranosyl (1 --> 2)-alpha-L-arabinopyranosyl]-28-O-[beta-D-allopyranosyl(1 --> 6)-beta-D-glucopyranosyl]-pomolic acid, and 3-O-[beta-D-grucopyranosyl(1 --> 3)-alpha-L-rhamnopyranosyl(l --> 2)-beta-D-xylopyranosyl]-28-O-[beta-D-allopyranosyl(1 --> 6)beta-D-glucopyranosyl]-pomolic acid, respectively, by the help of spectral evidence (IR, 1D- and 2D-NMR, FABMS). (C) 1998 Elsevier Science Ltd. All rights reserved.