Synthesis, crystal structure and thermoanalysis of bis{[mu-bis-N,N '-(2-hydroxybenzoyl)-1,3-propandiaminato](N,N '-dimethyl formamide) (mu- benzoato)nickel(II)}nickel(II)

Akay, Abdulkadir; Arici, Cengiz; Atakol, Orhan; Fuess, Hartmut; Svoboda, Ingrid

doi:10.1080/00958970500410374

Synthesis, crystal structure and thermoanalysis of bis{[mu-bis-N,N '-(2-hydroxybenzoyl)-1,3-propandiaminato](N,N '-dimethyl formamide) (mu- benzoato)nickel(II)}nickel(II)

Akay A., Arici C., Atakol O., Fuess H., Svoboda I.

JOURNAL OF COORDINATION CHEMISTRY, vol.59, no.8, pp.933-938, 2006 (SCI-Expanded, Scopus)

Publication Type: Article / Article
Volume: 59 Issue: 8
Publication Date: 2006
Doi Number: 10.1080/00958970500410374
Journal Name: JOURNAL OF COORDINATION CHEMISTRY
Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Page Numbers: pp.933-938
Hacettepe University Affiliated: No

Abstract

The title compound is a centrosymmetric, linear, homotrinuclear nickel(II) complex and has been characterized by elemental and thermogravimetric analysis, IR spectroscopy and single-crystal X-ray diffraction. The complex is monoclinic, space group P2(1)/n, with a = 13.707(4), b = 13.455(2), c = 14.620(3) angstrom, beta = 101.300(2)degrees, V = 2644.1(10) angstrom(3) and Z = 2. The central and terminal nickel( II) ions have distorted octahedral geometry with a Ni center dot center dot center dot Ni distance of 3.047(1) angstrom.