Crystal structure and Hirshfeld surface analysis of (Z)-N-{chloro[(4-ferrocenylphenyl)imino]methyl}-4-ferrocenylaniline N,N-dimethylformamide monosolvate

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Sghyar R., Bentama A., Haoudi A., Mazzah A., Mague J. T., HÖKELEK T., ...More

Acta Crystallographica Section E: Crystallographic Communications, vol.80, no.Pt 3, pp.262-266, 2024 (ESCI)

• Publication Type: Article / Article
• Volume: 80 Issue: Pt 3
• Publication Date: 2024
• Doi Number: 10.1107/s2056989024001002
• Journal Name: Acta Crystallographica Section E: Crystallographic Communications
• Journal Indexes: Emerging Sources Citation Index (ESCI), Scopus
• Page Numbers: pp.262-266
• Keywords: carbamidic chloride, crystal structure, C—H. . .π(ring) interactions, ferrocene, hydrogen bond
• Hacettepe University Affiliated: Yes

Abstract

The title molecule, [Fe2(C5H5)2(C23H17ClN2)]·C3H7NO, is twisted end to end and the central N/C/N unit is disordered. In the crystal, several C—H. . .π(ring) interactions lead to the formation of layers, which are connected by further C—H. . .π(ring) interactions. A Hirshfeld surface analysis of the crystal structure indicates that the most important contributions for the crystal packing are from H. . .H (60.2%) and H. . .C/C. . .H (27.0%) interactions. Hydrogen bonding, C—H. . .π(ring) interactions and van der Waals interactions dominate the crystal packing.