Crystal structure and Hirshfeld surface analysis of (Z)-N-{chloro[(4-ferrocenylphenyl)imino]methyl}-4-ferrocenylaniline N,N-dimethylformamide monosolvate

Sghyar R., Bentama A., Haoudi A., Mazzah A., Mague J. T., HÖKELEK T., ...Daha Fazla

Acta Crystallographica Section E: Crystallographic Communications, cilt.80, sa.Pt 3, ss.262-266, 2024 (ESCI) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 80 Sayı: Pt 3
  • Basım Tarihi: 2024
  • Doi Numarası: 10.1107/s2056989024001002
  • Dergi Adı: Acta Crystallographica Section E: Crystallographic Communications
  • Derginin Tarandığı İndeksler: Emerging Sources Citation Index (ESCI), Scopus
  • Sayfa Sayıları: ss.262-266
  • Anahtar Kelimeler: carbamidic chloride, crystal structure, C—H. . .π(ring) interactions, ferrocene, hydrogen bond
  • Hacettepe Üniversitesi Adresli: Evet

Özet

The title molecule, [Fe2(C5H5)2(C23H17ClN2)]·C3H7NO, is twisted end to end and the central N/C/N unit is disordered. In the crystal, several C—H. . .π(ring) interactions lead to the formation of layers, which are connected by further C—H. . .π(ring) interactions. A Hirshfeld surface analysis of the crystal structure indicates that the most important contributions for the crystal packing are from H. . .H (60.2%) and H. . .C/C. . .H (27.0%) interactions. Hydrogen bonding, C—H. . .π(ring) interactions and van der Waals interactions dominate the crystal packing.