Crystal structure of {[mu-bis(salicylidene)-1,3-propanediaminato]-copper(II)}dibromozinc(II)

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Ulku D., KAYNAK F. B., Atakol O., Aksu M.

ANALYTICAL SCIENCES, vol.19, no.5, pp.799-800, 2003 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 19 Issue: 5
  • Publication Date: 2003
  • Doi Number: 10.2116/analsci.19.799
  • Journal Name: ANALYTICAL SCIENCES
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.799-800
  • Hacettepe University Affiliated: Yes

Abstract

The title compound is a double oxygen-bridged dimeric heteronuclear metal complex. The coordination around the Cu atom is distorted square-planar involving two O and two N atoms from the bis(salicylidene)-1,3-propanediamine ligand. The Zn atom in the molecule has a distorted tetrahedral coordination sphere consisting of the two O atoms of the ligand and the two Br atoms. The bridging plane between the metal atoms is not planar.