Crystal structure of N-(3,4-dichlorophenyl)-N'-hydroxy-2-oxo-2-phenylacetamidine

Hokelek T., TAS M., BATI H.

CRYSTAL RESEARCH AND TECHNOLOGY, cilt.39, sa.4, ss.363-367, 2004 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 39 Sayı: 4
  • Basım Tarihi: 2004
  • Doi Numarası: 10.1002/crat.200310196
  • Dergi Adı: CRYSTAL RESEARCH AND TECHNOLOGY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.363-367
  • Hacettepe Üniversitesi Adresli: Evet

Özet

The title compound (C14H10N2O2Cl2) crystallizes in the monoclinic space group P2(1)/a with a=10.042(l) Angstrom, b-10.317(1)`Angstrom,c=13.877(2)Angstrom, beta-97.36(2)degrees,V=l425.8(3)Angstrom (3), Z 4, D-x- 1.44 g.Cm-3. The structure was solved by direct methods and refined by full-matrix least-squares method (R=0.0457). The title molecule consists of 3,4-dichlorophenylamino and 2-phenyl-1,2-ethanedione-1-oxime groups. The intermolecular O-H...N and N-H...O hydrogen bonds [O...N 2.760(6) and 3.087(5) A] are highly effective in forming the polymeric chains. The oxime group has an E configuration. (C) 2004 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.