Chemical exfoliation characteristics of Karakoc phlogopite in hydrogen peroxide solution

Ucgul E., Girgin I.

TURKISH JOURNAL OF CHEMISTRY, vol.26, no.3, pp.431-439, 2002 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 26 Issue: 3
  • Publication Date: 2002
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, TR DİZİN (ULAKBİM)
  • Page Numbers: pp.431-439
  • Hacettepe University Affiliated: Yes


The chemical exfoliation characteristics of phlogopite samples taken from Sivas-Yildizeli-Karakoc (Turkey) ore were investigated. H2SO4, HCl, HNO3, H3PO4 and H2O2 solutions at varying concentrations were tested for chemical exfoliation and the best reagent for this purpose was determined to be hydrogen peroxide. In the exfoliation tests performed, hydrogen peroxide concentration, temperature and reaction time were observed to be important parameters, with solid/liquid ratio being of minor importance. The exfoliation characteristics of the material increased with increases in hydrogen peroxide concentration and depending on the reaction time (1-30 hours) a maximum value of a 49-fold increase in swelling was obtained in 30% hydrogen peroxide solution at room temperature with a change of the density from 2.75 g/cm(3) to 0.37 g/cm(3). Although maximum swelling was reached in 30 hours at room temperature in 30% hydrogen peroxide solution, the reaction time was lowered to 70 minutes by an increase in temperature to 60degreesC. Above 60degreesC the material started to decompose into fine particles, with complete loss of its characteristics above 80degreesC. The experimental results were interpreted mathematically and a regression model was proposed to calculate the swelling ratio for any hydrogen peroxide concentration and reaction time at room temperature.