Spectroscopic and structural studies on dichlorobis(nicotinamide)zinc(II)

İDE S., Atac A., Yurdakul S.

JOURNAL OF MOLECULAR STRUCTURE, vol.605, no.1, pp.103-107, 2002 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 605 Issue: 1
  • Publication Date: 2002
  • Doi Number: 10.1016/s0022-2860(01)00747-5
  • Journal Name: JOURNAL OF MOLECULAR STRUCTURE
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.103-107
  • Keywords: nicotinamide, pyridine ring, crystal
  • Hacettepe University Affiliated: Yes

Abstract

ZnCl2(C6H6N2O)(2) Complex was prepared and investigated. The stoichiometry of this complex was derived from the results of elemental analysis and infrared spectroscopic studies. The crystal and molecular structure of the complex was also crystallographically characterized, to obtain a certain structure. The Zn(II) atom is coordinated by two chloride ligands and two N atoms from the nicotinamide ligands, in a distorted tetrahedral coordination environment, with Zn-N distances 2.058(3) and 2.057(4) Angstrom, Zn-Cl distances of 2.221(1) and 2.209(1) Angstrom and N-Zn-N and Cl-Zn-Cl angles of 101.8(1) and 121.81(5)degrees, respectively. (C) 2002 Published by Elsevier Science B.V.