The enhanced enzymatic performance of carbonic anhydrase on the reaction rate between CO(2)and aqueous solutions of sterically hindered amines


Cihan N., YÜKSEL ORHAN Ö.

GREENHOUSE GASES-SCIENCE AND TECHNOLOGY, cilt.10, ss.925-937, 2020 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 10 Konu: 5
  • Basım Tarihi: 2020
  • Doi Numarası: 10.1002/ghg.2012
  • Dergi Adı: GREENHOUSE GASES-SCIENCE AND TECHNOLOGY
  • Sayfa Sayıları: ss.925-937

Özet

The kinetics of the reactions of carbon dioxide (CO2) with aqueous solutions of two different sterically hindered amines (SHAs), 2-amino-2-ethyl-1,3-propanediol (AEPD) and 2-amino-2-methyl-1,3-propanediol (AMPD), in the presence and absence of carbonic anhydrase (CA) was investigated experimentally using stopped-flow conductimetry. The amine concentration, CA concentration, and temperature were varied within the ranges of 0.1-0.5 kmol center dot m(-3), 0-125 g center dot m(-3), and 298-353 K, respectively. Based on pseudo first-order reaction conditions, the intrinsic reaction rate (k(o)) was obtained according to a modified termolecular reaction mechanism. The obtained results showed that the reaction rate between the SHA solutions (either aqueous AEPD or aqueous AMPD) and CO(2)was enhanced significantly upon adding small amounts of CA as a promoter. Such a result supports the use of the aforementioned solvent system as a candidate for CO(2)capture. (c) 2020 Society of Chemical Industry and John Wiley & Sons, Ltd.