2,4,4,6,6-Pentachloro-2-(2,6-di-tert-butyl-4-methylphenoxy)cyclo-2 lambda(5),4 lambda(5),6 lambda(5)-triphosphazatriene

Hokelek, TUNCER; KILIC, A; BEGEC, S; KILIC, Z

doi:10.1107/s0108270198016941

2,4,4,6,6-Pentachloro-2-(2,6-di-tert-butyl-4-methylphenoxy)cyclo-2 lambda(5),4 lambda(5),6 lambda(5)-triphosphazatriene

Hokelek T. , KILIC A., BEGEC S., KILIC Z.

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, cilt.55, ss.783-785, 1999 (SCI İndekslerine Giren Dergi)

Cilt numarası: 55
Basım Tarihi: 1999
Doi Numarası: 10.1107/s0108270198016941
Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
Sayfa Sayıları: ss.783-785

Özet

The title compound, C15H23Cl5N3OP3, consists of a non-planar trimeric phosphazene ring and a bulky 2,6-di-tert-butyl-4-methylphenoxy side group in which the phenyl ring shows a small but significant distortion from planarity. The bulky group predominantly determines the molecular shape. The endocyclic angle about the P atom bonded to the substituent is decreased, while the exocyclic angle is increased. The situation is not similar to that of tetrameric phosphazene derivatives.