Spectroelectrochemical investigations of aniline-thiophene copolymers in acetonitrile


ÖZÇİÇEK N. , Pekmez K., Holze R., Yildiz A.

JOURNAL OF APPLIED POLYMER SCIENCE, cilt.90, ss.3417-3423, 2003 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 90 Konu: 12
  • Basım Tarihi: 2003
  • Doi Numarası: 10.1002/app.13035
  • Dergi Adı: JOURNAL OF APPLIED POLYMER SCIENCE
  • Sayfa Sayıları: ss.3417-3423

Özet

The copolymerization of aniline and thiophene with varying concentration ratios was studied in acetonitrile/tetrabutylammonium tetrafloroborate. In situ UV-vis and in situ surface resonance Raman spectroscopic studies revealed that polythiophene and polyaniline units of different lengths enter into the electropolymerization products. The copolymers deposited were either polyaniline-based or polythiophene-based polymeric structures depending on the initial concentration of the monomers used. (C) 2003 Wiley Periodicals, Inc.