Enrichment and Separation of Fe(III), Mn(II), Ni(II), and Zn(II) as Their Congo Red Chelates on Multiwalled Carbon Nanotube (MWCNT) Disk in Food and Water Samples


Durukan I. , SOYLAK M., Dogan M.

ATOMIC SPECTROSCOPY, cilt.34, ss.20-25, 2013 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 34 Konu: 1
  • Basım Tarihi: 2013
  • Dergi Adı: ATOMIC SPECTROSCOPY
  • Sayfa Sayıları: ss.20-25

Özet

In this study, a novel method of using multiwalled carbon nanotube disk-solid phase extraction (MWCNT disk-SPE) of iron, manganese, nickel, and zinc in food and water samples is described. Congo Red (CR) was used as the chelating agent. The analytical parameters of the MWCNT disk-SPE system, including pH, amount of CR, sample volume, type of eluent, and sample flow rates, were investigated. Detection limits of 4.2, 1.2, 2.1, and 1.8 ng/mL for iron, manganese, nickel, and zinc, respectively, were obtained and a preconcentration factor of 25 was achieved. The SPE technique was applied to the determination of analyte elements in certified reference materials, water and food samples with satisfactory results.