Crystal structure analysis of {bis-2,6-(3,5-dimethylprazolyl) pyridine-dicyanato}copper(II)monohydrate

Arici C., Ulku D., Kurtaran R., Ergun U., Atakol O.

CRYSTAL RESEARCH AND TECHNOLOGY, cilt.41, sa.3, ss.309-313, 2006 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 41 Sayı: 3
  • Basım Tarihi: 2006
  • Doi Numarası: 10.1002/crat.200510579
  • Dergi Adı: CRYSTAL RESEARCH AND TECHNOLOGY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.309-313
  • Hacettepe Üniversitesi Adresli: Hayır

Özet

A monotruclear copper(II) complex, [Cu(dmpp)(OCN)(2)(H2O)], was synthesized using 2,6-bis (3,5-dimethylpyrazolyl) pyridine (dmpp) and cyanate anion (OCN), and characterized by single crystal X-ray diffraction. The coordination around the Cu atom is a distorted square-pyramid involving three N atoms from the dmpp ligand and one N atom from OCN at the basal plane. The 0 atom of the OCN group is located at the apical position. The Cu atom is located 0.2782(1) angstrom above the basal plane. The Cu atom is coordinated by different donor atoms of the OCN groups. The complex crystalizes in monoclinic space group P2(1)/n, with unit cell dimensions a= 12.4413(12), b=11.1457(13), c=14.2203(12) angstrom, beta=108.817(3)degrees, V= 1866.5(3) angstrom(3). The cell containes 4 molecules. In the crystal, there are three intermolcular and three intramolecular hydrogen bonds interactions. The Cu atom and crystal water O interactions is 5.574 angstrom.