Synthesis, crystal structure and electrochemical behaviour of [2,6-bis(3,5-dimethylpyrazolyl)pyridine](dithiocyanato)cobalt(II)


Arici C., Ulku D., Kurtaran R., Emregul K., Atakol O.

ZEITSCHRIFT FUR KRISTALLOGRAPHIE, cilt.218, ss.497-500, 2003 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 218 Konu: 7
  • Basım Tarihi: 2003
  • Doi Numarası: 10.1524/zkri.218.7.497.20707
  • Dergi Adı: ZEITSCHRIFT FUR KRISTALLOGRAPHIE
  • Sayfa Sayıları: ss.497-500

Özet

A mononuclear cobalt(II) complex, [Co(dmpp)(SCN)(2)], was synthesized using 2,6-bis (3,5-di-methylpyrazolyl)pyridine (dmpp) and thiocyanate anion (SCN), and characterized by IR spectroscopy and single-crystal X-ray diffraction. In addition, cyclic voltammetric studies have been performed. The complex crystalizes in monoclinic space group C 2/c, with unit cell dimensions a = 15.2469(15), b = 9.1120(9), c = 14.0302(11) Angstrom, beta = 95.823(3)degrees. The cell containes 4 molecules.