Synthesis, crystal structure and electrochemical behaviour of [2,6-bis(3,5-dimethylpyrazolyl)pyridine](dithiocyanato)cobalt(II)


Arici C., Ulku D., Kurtaran R., Emregul K., Atakol O.

ZEITSCHRIFT FUR KRISTALLOGRAPHIE, vol.218, no.7, pp.497-500, 2003 (Peer-Reviewed Journal) identifier identifier

  • Publication Type: Article / Article
  • Volume: 218 Issue: 7
  • Publication Date: 2003
  • Doi Number: 10.1524/zkri.218.7.497.20707
  • Journal Name: ZEITSCHRIFT FUR KRISTALLOGRAPHIE
  • Journal Indexes: Science Citation Index Expanded, Scopus
  • Page Numbers: pp.497-500

Abstract

A mononuclear cobalt(II) complex, [Co(dmpp)(SCN)(2)], was synthesized using 2,6-bis (3,5-di-methylpyrazolyl)pyridine (dmpp) and thiocyanate anion (SCN), and characterized by IR spectroscopy and single-crystal X-ray diffraction. In addition, cyclic voltammetric studies have been performed. The complex crystalizes in monoclinic space group C 2/c, with unit cell dimensions a = 15.2469(15), b = 9.1120(9), c = 14.0302(11) Angstrom, beta = 95.823(3)degrees. The cell containes 4 molecules.