Structure and electrochemical behaviour of Bis[N-(4-methylphenyl)salicylaldimine]copper(II) N,N '-dimethylformamide solvate


Yildirim L. , EMREGUL K. C. , KURTARAN R., ATAKOL O.

CRYSTAL RESEARCH AND TECHNOLOGY, cilt.37, ss.1344-1351, 2002 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 37 Konu: 12
  • Basım Tarihi: 2002
  • Doi Numarası: 10.1002/crat.200290012
  • Dergi Adı: CRYSTAL RESEARCH AND TECHNOLOGY
  • Sayfa Sayıları: ss.1344-1351

Özet

The molecular model of mononuclear complex formed, through a reaction between N-(4-methylphenyl)salicylaldimine and Cu-II ion was determined using x-ray diffraction method. The Cu-II coordination was found to have a distorted square-planar structure and a cis coordination geometry was observed within the surrounding of the copper. The electro chemical behaviour of the mononuclear copper complex was studied with cyclic voltammetry.