4,4,6,6-tetrachloro-2,2-(propylenedioxydi-o-phenylenediimino)-2 lambda(5),4 lambda(5),6 lambda(5)-cyclotriphosphazene


TERCAN B., Hokelek T. , BILGE S., OZGUC Z., KILIC Z.

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, cilt.60, 2004 (SCI İndekslerine Giren Dergi) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 60
  • Basım Tarihi: 2004
  • Doi Numarası: 10.1107/s0108270104006894
  • Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY

Özet

The title compound, C15H16Cl4N5O2P3, is a cyclophosphazenic lariat (PNP-pivot) ether with a spiro-cyclic 12-membered macrocyclic ligand containing two ether O and two N atoms; the phosphazene ring is nearly planar. In the macrocyclic ring, there is a four-center (trifurcate) N-H...O/N-H...N hydrogen bond. The relative inner-hole size of the macrocycle is estimated as approximately 0.95 Angstrom.