(Ketoprofenato)trimethyltin(IV)

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Tahir M., Ulku D., Ali S., Masood T., Danish M., Mazhar M.

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, pp.1574-1576, 1997 (SCI-Expanded)

• Publication Type: Article / Article
• Publication Date: 1997
• Doi Number: 10.1107/s0108270197007348
• Journal Name: ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
• Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED)
• Page Numbers: pp.1574-1576
• Hacettepe University Affiliated: No

Abstract

In the title compound, [Sn(CH3)(3)(C16H13O3)], the Sn atom has fivefold coordination involving three methyl C atoms defining the equatorial plane of a trigonal bipyramid and two O atoms from two carboxylate groups occupying the axial positions. The Sn-C bond lengths [2.106(6), 2.110(5) and 2.116(5)Angstrom] are very similar. The two carboxylate O atoms have notably different distances to the metal atom [2.184(3) and 2.433 (4) Angstrom], with an O-Sn-O angle of 174.0(1)degrees. Bidentate bridging of the carboxylate ligands via trimethyltin groups forms a polymeric structure.