Adsorption of mercury(II) ions by poly(hydroxyethylmethacryl ate) adsorbents with thiazolidine groups

Arpa Ç., Saglam A., Bektas S., Patir S., Genc O., Denizli A.

ADSORPTION SCIENCE & TECHNOLOGY, vol.20, no.3, pp.203-213, 2002 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 20 Issue: 3
  • Publication Date: 2002
  • Doi Number: 10.1260/026361702760254405
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.203-213
  • Hacettepe University Affiliated: Yes


A wide variety of adsorbents has been reported in the literature for heavy metal adsorption. We have recently developed a new polymer system for the removal of contaminant heavy metal ions from aquatic systems. Thus, poly(hydroxyethylmethacrylate) (PHEMA) microbeads carrying thiazolidine (0.318 mmol/g) were prepared for the removal of different amounts of mercury(II) ions (50-900 mg/l) from aqueous solutions and at different pH values (3.0-7.0). Adsorption rates were high with adsorption equilibria being reached within 10 min. The adsorption of Hg(II) ions on to the thiazolidine-immobilized microbeads from single solutions amounted to 1.11 mmol/g. The formation constant of the thiazolidine-metal ion complex was investigated by the method of Ruzic. The calculated value of the stability constant was 9.11 x 10(5) l/mol for the Hg(II)-thiazolidine complex. PHEMA microbeads carrying thiazolidine may be regenerated by washing with a solution of hydrochloric acid (0.05 M). The maximum desorption ratio was as high as 99%. These PHEMA microbeads may be used repeatedly for more than three adsorption/desorption cycles without any considerable loss in adsorption capacity.