TETRAKIS(MU-BENZOATO-O-O')BIS(N,N-DIETHYLNICOTINAMIDE-N')DICOPPER(II)


HOKELEK T. , NECEFOGLU H., BALCI M. N.

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, cilt.51, ss.2020-2023, 1995 (SCI İndekslerine Giren Dergi) identifier

  • Cilt numarası: 51
  • Basım Tarihi: 1995
  • Doi Numarası: 10.1107/s0108270195000618
  • Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
  • Sayfa Sayıları: ss.2020-2023

Özet

The title molecule, [CU2(Cu6H5COO)(4)(C10H14N2O)(2)], is a crystallographically centrosymmetric binuclear complex, with Cu atoms [Cu...Cu' = 2.613 (1) Angstrom] bridged by four benzoate ligands. The four nearest O atoms around each Cu atom form a square-planar arrangement with the square-pyramidal coordination completed by the pyridine N atom of the N,N(-diethylnicotinamide ligand at a distance of 2.162(6) Angstrom. Each Cu atom is displaced by 0.190 (1) Angstrom from the plane of the four O atoms, with an average Cu-O distance of 1.974(6) Angstrom.