TETRAKIS(MU-BENZOATO-O-O')BIS(N,N-DIETHYLNICOTINAMIDE-N')DICOPPER(II)

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HOKELEK T., NECEFOGLU H., BALCI M. N.

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, vol.51, pp.2020-2023, 1995 (SCI-Expanded)

• Publication Type: Article / Article
• Volume: 51
• Publication Date: 1995
• Doi Number: 10.1107/s0108270195000618
• Journal Name: ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
• Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Academic Search Premier, Aerospace Database, Communication Abstracts, Metadex, Civil Engineering Abstracts
• Page Numbers: pp.2020-2023
• Hacettepe University Affiliated: Yes

Abstract

The title molecule, [CU2(Cu6H5COO)(4)(C10H14N2O)(2)], is a crystallographically centrosymmetric binuclear complex, with Cu atoms [Cu...Cu' = 2.613 (1) Angstrom] bridged by four benzoate ligands. The four nearest O atoms around each Cu atom form a square-planar arrangement with the square-pyramidal coordination completed by the pyridine N atom of the N,N(-diethylnicotinamide ligand at a distance of 2.162(6) Angstrom. Each Cu atom is displaced by 0.190 (1) Angstrom from the plane of the four O atoms, with an average Cu-O distance of 1.974(6) Angstrom.