Bis(4-fluorobenzoato-kappa O-2,O ')bis-(nicotinamide-kappa N-1)zinc(II)monohydrate
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.64, 2008 (SCI-Expanded, ESCI, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 64
- Basım Tarihi: 2008
- Doi Numarası: 10.1107/s1600536808003747
- Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Emerging Sources Citation Index (ESCI), Scopus
- Açık Arşiv Koleksiyonu: AVESİS Açık Erişim Koleksiyonu
- Hacettepe Üniversitesi Adresli: Evet
Özet
The title compound, [Zn(C7H4FO2)(2)(C6H6N2O)(2)]center dot H2O, is a monomeric complex. It contains two 4-fluorobenzoate and two nicotinamide ligands and one uncoordinated water molecule. The 4-fluorobenzoates act as bidentate chelating ligands, while the nicotinamides are monodentate. The sixcoordinate geometry around the Zn-II atom may be described as highly distorted octahedral, with the two nicotinamide ligands arranged cis. Intermolecular O - H center dot center dot center dot O and N - H center dot center dot center dot O hydrogen bonds link the molecules into a supramolecular structure.