Electrochemical polymerization of benzene in the presence of Ag+, Pb2+ and Cu+ ions


Ersöz A., Arca M., PEKMEZ K., Yildiz A.

Materials Research Innovations, cilt.4, sa.2-3, ss.126-130, 2001 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 4 Sayı: 2-3
  • Basım Tarihi: 2001
  • Doi Numarası: 10.1007/s100190000082
  • Dergi Adı: Materials Research Innovations
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.126-130
  • Anahtar Kelimeler: Conducting polymers, Electrooxidation of benzene, Poly(p-phenylene)
  • Hacettepe Üniversitesi Adresli: Evet

Özet

Poly(p-phenylene) (PPP) films were synthesized by using benzene and fluorosulphonic acid (FSO3H) as a strong acid containing Ag+, Pb2+ and Cu+ ions in methylene chloride (CH2Cl2) solution. Addition of Ag+ or Pb2+ ions into the polymerization medium improved the PPP films formation, but Cu+ ion did not have an effect on polymerization. PPP films were characterized by cyclic voltammetry, IR and TGA. Dry conductivities were measured by using four probe technique.