Synthesis, complex formation, spectral and crystallographic investigations of new crown ethers containing recognition site for sodium. Part V


HAYVALI Z., HAYVALI M., KILIC Z., Hokelek T.

JOURNAL OF MOLECULAR STRUCTURE, cilt.597, ss.223-234, 2001 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 597
  • Basım Tarihi: 2001
  • Doi Numarası: 10.1016/s0022-2860(01)00603-2
  • Dergi Adı: JOURNAL OF MOLECULAR STRUCTURE
  • Sayfa Sayıları: ss.223-234

Özet

The monotopic crown ether ligands (5 and 6) and their sodium perchlorate complexes (5a and 6a) have been synthesized. The crystal structure of (5) has been determined, which contains 1 mol of water molecule. Compound (5) crystallizes in the monoclinic space group C2/c with a = 39.324(8), b = 8.011(1), c = 16.877(4) Angstrom, beta = 107.61(2)degrees, V = 5067.5(2) Angstrom (3), Z = 8 and D-calc = 1.289 g m(-3).