Synthesis, complex formation, spectral and crystallographic investigations of new crown ethers containing recognition site for sodium. Part V

HAYVALI, Z; HAYVALI, M; KILIC, Z; Hokelek, TUNCER

doi:10.1016/s0022-2860(01)00603-2

Synthesis, complex formation, spectral and crystallographic investigations of new crown ethers containing recognition site for sodium. Part V

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HAYVALI Z., HAYVALI M., KILIC Z., Hokelek T.

JOURNAL OF MOLECULAR STRUCTURE, vol.597, pp.223-234, 2001 (SCI-Expanded)

Publication Type: Article / Article
Volume: 597
Publication Date: 2001
Doi Number: 10.1016/s0022-2860(01)00603-2
Journal Name: JOURNAL OF MOLECULAR STRUCTURE
Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Page Numbers: pp.223-234
Hacettepe University Affiliated: Yes

Abstract

The monotopic crown ether ligands (5 and 6) and their sodium perchlorate complexes (5a and 6a) have been synthesized. The crystal structure of (5) has been determined, which contains 1 mol of water molecule. Compound (5) crystallizes in the monoclinic space group C2/c with a = 39.324(8), b = 8.011(1), c = 16.877(4) Angstrom, beta = 107.61(2)degrees, V = 5067.5(2) Angstrom (3), Z = 8 and D-calc = 1.289 g m(-3).