Structural information on transition metal(II) complexes of 4,4 '-bipyridyl and 4-phenylpyridine from their infrared spectra


Bayari S. , Topacli A., Salih B.

JOURNAL OF MOLECULAR STRUCTURE, cilt.482, ss.165-169, 1999 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 482
  • Basım Tarihi: 1999
  • Doi Numarası: 10.1016/s0022-2860(98)00845-x
  • Dergi Adı: JOURNAL OF MOLECULAR STRUCTURE
  • Sayfa Sayıları: ss.165-169

Özet

The infrared spectra (4000-300 cm(-1)) are reported for metal(II) chloro 4,4'-bipyridyl and 4-phenylpyridine complexes and metal(II)-isothiocyanate 4-phenylpyridine complexes of the following stoichiometries: [M(bipy)Cl(2)] {M = Mn, Fe, Co or Ni}, [M(4-phpy)(2)Cl(2)] {M = Fe, Co, Cd, Zn, Cu, Hg or Pd} and [M(4-phpy)(n)(NCS)(2)] {n = 2, M = Co, Ni, Zn or Cu; n = 4, M = Fe or Ni} and an assignment is proposed for all the infrared bands. (C) 1999 Elsevier Science B.V. All rights reserved.