Synthesis and Characterization of 1,2-Benzenedimethyloxy Substituted Novel Ball-Type and Mononuclear Metallo Phthalocyanines

Yazici A., Dalbul N., SALİH B.

JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN, vol.36, no.4, pp.707-711, 2014 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 36 Issue: 4
  • Publication Date: 2014
  • Journal Name: JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.707-711
  • Hacettepe University Affiliated: Yes

Abstract

The phthalodinitrile derivative 1 was synthesized by the reaction of 1,2-benzenedimethanol and 4-nitrophthalonitrile in dry DMF in the presence of K2CO3 by the common method of nucleophilic substitution of an activated nitro group in an aromatic ring. The template reaction of 1 with the corresponding metal salts gave the novel mono-nuclear ZnPc 2 and ball-type metallophthalocyanine LuPc2 3.