Synthesis and Characterization of 1,2-Benzenedimethyloxy Substituted Novel Ball-Type and Mononuclear Metallo Phthalocyanines


Yazici A., Dalbul N., SALİH B.

JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN, cilt.36, sa.4, ss.707-711, 2014 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 36 Sayı: 4
  • Basım Tarihi: 2014
  • Dergi Adı: JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.707-711
  • Hacettepe Üniversitesi Adresli: Evet

Özet

The phthalodinitrile derivative 1 was synthesized by the reaction of 1,2-benzenedimethanol and 4-nitrophthalonitrile in dry DMF in the presence of K2CO3 by the common method of nucleophilic substitution of an activated nitro group in an aromatic ring. The template reaction of 1 with the corresponding metal salts gave the novel mono-nuclear ZnPc 2 and ball-type metallophthalocyanine LuPc2 3.