Dichlorobis[2-(o-tolyliminiomethyl)-phenolato-O]zinc(II)


Ulku D., Arici C., Tahir M., Atakol O.

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, vol.56, pp.1298-1299, 2000 (Peer-Reviewed Journal) identifier

  • Publication Type: Article / Article
  • Volume: 56
  • Publication Date: 2000
  • Doi Number: 10.1107/s0108270100009008
  • Journal Name: ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
  • Journal Indexes: Science Citation Index Expanded
  • Page Numbers: pp.1298-1299

Abstract

In the mononuclear title compound, [ZnCl2(C14H13NO)(2)], the Zn-II ion is located on a twofold axis of the monoclinic space group so that the whole molecule has a twofold symmetry. The Zn-II ion has a tetrahedral coordination consisting of two chlorine ions and the O atoms of the ligands. The coordination angles around zinc have values between 102.89 (8) (O-Zn-O) and 115.83 (5)degrees (Cl-Zn-O). The Zn-O and Zn-Cl bond lengths are 1.977 (2) and 2.2401 (7) Angstrom, respectively. There are intra- and intermolecular hydrogen bonds in the structure.