Dichlorobis[2-(o-tolyliminiomethyl)-phenolato-O]zinc(II)


Ulku D., Arici C., Tahir M., Atakol O.

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, cilt.56, ss.1298-1299, 2000 (SCI İndekslerine Giren Dergi) identifier

  • Cilt numarası: 56
  • Basım Tarihi: 2000
  • Doi Numarası: 10.1107/s0108270100009008
  • Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
  • Sayfa Sayıları: ss.1298-1299

Özet

In the mononuclear title compound, [ZnCl2(C14H13NO)(2)], the Zn-II ion is located on a twofold axis of the monoclinic space group so that the whole molecule has a twofold symmetry. The Zn-II ion has a tetrahedral coordination consisting of two chlorine ions and the O atoms of the ligands. The coordination angles around zinc have values between 102.89 (8) (O-Zn-O) and 115.83 (5)degrees (Cl-Zn-O). The Zn-O and Zn-Cl bond lengths are 1.977 (2) and 2.2401 (7) Angstrom, respectively. There are intra- and intermolecular hydrogen bonds in the structure.