Removal of chromium(VI) ions from synthetic solutions by the fungus Penicillium purpurogenum

Say R., Yilmaz N., Denizli A.

ENGINEERING IN LIFE SCIENCES, cilt.4, sa.3, ss.276-280, 2004 (SCI İndekslerine Giren Dergi) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 4 Konu: 3
  • Basım Tarihi: 2004
  • Doi Numarası: 10.1002/elsc.200420032
  • Sayfa Sayıları: ss.276-280


The ability of Penicillium purpurogenum to bind high amounts of chromium(VI) from aqueous solutions is demonstrated. Cr(VI) adsorption capacity increases with time during the first four hours and then leveled off toward the equilibrium adsorption capacity. Biosorption of Cr(VI) ions reached equilibrium in four hours. Binding of Cr(VI) ions with Penicillium purpurogenum biomass was clearly pH dependent. Cr(VI) loading capacity increased with increasing pH. The adsorption of Cr(VI) ions reached a plateau value at a pH of approx. 6.0. The maximum capacity of adsorption of Cr(VI) ions onto the fungal biomass was 36.5 mg/g. Adsorption behavior of Cr(VI) ions can be approximately described with the Langmuir equation. When applying the Langmuir model, the maximum adsorption capacity (Q(max)) and the Langmuir constant were found to be 40 mg/g and 3.9 x 10(-3) mg/L. Elution of Cr(VI) ions was performed by means of 0.5 M HCl. It was possible to use the biomass of Penicillium purpurogenum for six cycles for biosorption.