An infrared and Raman spectroscopic study on the solvation of mercury(II) cyanide in aprotic donor solvents


Gurcay D. , KANTARCI Z., AYDIN S.

JOURNAL OF MOLECULAR STRUCTURE, cilt.482, ss.65-68, 1999 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 482
  • Basım Tarihi: 1999
  • Doi Numarası: 10.1016/s0022-2860(98)00838-2
  • Dergi Adı: JOURNAL OF MOLECULAR STRUCTURE
  • Sayfa Sayıları: ss.65-68

Özet

Evidence based on the IR and Raman spectral features of HE(CN)(2) in twelve solvents with widely different donor strengths supports the view that increasing solvent coordination to the Hg atom leads to a progressive reduction of the C-Hg-C angle from 180 degrees. For solvents of high donor strength (e.g. piperidine) the C-Hg-C interbond angle may approach 145 degrees. (C) 1999 Elsevier Science B.V. All rights reserved.