Pyrolysis kinetics of blends of Yeni Celtek lignite and sugar beet pulp
ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS, cilt.30, sa.3, ss.238-246, 2008 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 30 Sayı: 3
- Basım Tarihi: 2008
- Doi Numarası: 10.1080/00908310600712646
- Dergi Adı: ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.238-246
- Hacettepe Üniversitesi Adresli: Hayır
Özet
Pyrolysis kinetics of the Yeni eltek lignite/sugar beet pulp blends prepared at different ratios (100:0, 80:20, 60:40, 40:60, 20:80, and 0:100) were investigated by thermogravimetric analysis in the present study. All the experiments were carried out in nitrogen atmosphere under non-isothermal conditions with a heating rate range of 30 K/min in the pyrolysis temperature interval of 298-1,173 K. The Arrhenius model is applied to determine the kinetic parameters from TG/DTG curves. Apparent activation energies of the lignite and sugar beet pulp were calculated as 51.55 kJ/mol and 97.27 kJ/mol, respectively. Activation energies of the blends were also calculated and were found to vary between 54.87 and 74.83 kJ/mol. Effects of blending ratio of lignite to sugar beet pulp on kinetic parameters were investigated and the results were discussed.