Synthesis of meso-pyrrole-substituted corroles by condensation of 1,9-diformyldipyrromethanes with pyrrole

Creative Commons License

TEMELLİ B., Kapci P.

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, vol.18, pp.1403-1409, 2022 (SCI-Expanded) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: 18
  • Publication Date: 2022
  • Doi Number: 10.3762/bjoc.18.145
  • Journal Name: BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Aquatic Science & Fisheries Abstracts (ASFA), Biotechnology Research Abstracts, Chemical Abstracts Core, Directory of Open Access Journals
  • Page Numbers: pp.1403-1409
  • Keywords: corrole, dipyrromethane, macrocycles, metal triflates, pyrrole, SPECTROSCOPIC PROPERTIES, PORPHYRINS, BEARING
  • Hacettepe University Affiliated: Yes

Abstract

A copper triflate-mediated approach to access copper complexes of pyrrole-substituted corroles from the reaction of 1,9-diformyldipyrromethanes and an excess amount of pyrrole is presented for the first time. This procedure is a simple and efficient way for the preparation of corroles with a polymerizable substituent on meso-positions.