Synthesis of meso-pyrrole-substituted corroles by condensation of 1,9-diformyldipyrromethanes with pyrrole

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TEMELLİ B., Kapci P.

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, cilt.18, ss.1403-1409, 2022 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 18
  • Basım Tarihi: 2022
  • Doi Numarası: 10.3762/bjoc.18.145
  • Dergi Adı: BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Aquatic Science & Fisheries Abstracts (ASFA), Biotechnology Research Abstracts, Chemical Abstracts Core, Directory of Open Access Journals
  • Sayfa Sayıları: ss.1403-1409
  • Anahtar Kelimeler: corrole, dipyrromethane, macrocycles, metal triflates, pyrrole, SPECTROSCOPIC PROPERTIES, PORPHYRINS, BEARING
  • Hacettepe Üniversitesi Adresli: Evet

Özet

A copper triflate-mediated approach to access copper complexes of pyrrole-substituted corroles from the reaction of 1,9-diformyldipyrromethanes and an excess amount of pyrrole is presented for the first time. This procedure is a simple and efficient way for the preparation of corroles with a polymerizable substituent on meso-positions.