Synthesis, structural and spectral studies of bis-[N-(2,4-dimethoxy benzylidene)-2-mercaptoanilinato] Ni(II)

Sahin E., Ide S., Ancin N., Oztas S., Tuzun M.

ZEITSCHRIFT FUR KRISTALLOGRAPHIE, vol.217, no.4, pp.174-177, 2002 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 217 Issue: 4
  • Publication Date: 2002
  • Doi Number: 10.1524/zkri.217.4.174.20642
  • Journal Name: ZEITSCHRIFT FUR KRISTALLOGRAPHIE
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.174-177
  • Hacettepe University Affiliated: Yes

Abstract

The Ni(II) complex of N-(2,4-dimethoxy benzylidene)-2-mercaptoaniline, [Ni(C15H14NO2S)(2)] was prepared and investigated. The structure derived from the two dimensional (2-D) NMR techniques, the infrared spectra, elemental analysis and mass spectra is consistent with that of the single crystal X-ray diffraction. Crystal system is monoclinic, space group Cc(no:9), number of formulae per unit cell Z = 4. Cell parameters are a = 14.283(4), b = 13.828(4), c = 14.345(5) Angstrom, beta = 102.84(3), V = 2762(2) Angstrom(3). Two singly deprotonated ligands coordinate the metal atom in a distorted square planar geometry. The molecular geometry was also effected by C-H...N and C-H...O intramolecular hydrogen bonds.