Complex formation of linear poly (methacrylic acid) with uranyl ions in aqueous solutions


Azhgozhinova G., Guven O., Pekel N., Dubolazov A., Mun G., Nurkeeva Z.

JOURNAL OF COLLOID AND INTERFACE SCIENCE, vol.278, no.1, pp.155-159, 2004 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 278 Issue: 1
  • Publication Date: 2004
  • Doi Number: 10.1016/j.jcis.2004.05.010
  • Title of Journal : JOURNAL OF COLLOID AND INTERFACE SCIENCE
  • Page Numbers: pp.155-159

Abstract

The complex formation of uranyl ions (UO22+) with poly(methacrylic acid) (PMAA) was investigated by potentiometric, conductometric, UV-visible, luminescence and FTIR spectroscopic, and thermal analysis methods. The stoichiometric ratio at complexation between polymer complex confirmed and uranyl ions was found to be equal to 2 polymer base units per uranyl ion. FTIR spectra of the PMAA-UO22+ incorporation of metal ions into the polymer and showed that the electrostatic interactions play a major role in complexation. An increase of emission intensity in luminescence spectra of uranyl ions suggests influence of conformation peculiarity of the poly(methacrylic acid) chain. The thermal degradation of polycomplex starts at lower temperature as compared to pristine PMAA that is due to the lower thermal stability of PMAA-UO22+ complex. (C) 2004 Elsevier Inc. All rights reserved.