Synthesis and crystal structure of hexahydrobis[(1,3-p-dimethylaminobenzyl)-1,3-diazepinel-2-selenone, C23H32N4Se


Aygun M. , Cetinkaya E., Gok Y., Kendi E., Cetinkaya B.

ANALYTICAL SCIENCES, vol.19, no.7, pp.1093-1094, 2003 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 19 Issue: 7
  • Publication Date: 2003
  • Doi Number: 10.2116/analsci.19.1093
  • Title of Journal : ANALYTICAL SCIENCES
  • Page Numbers: pp.1093-1094

Abstract

In the title compound, C23H32N4Se, was synthesized and its crystal structure was determined by single crystal X-ray diffraction. The compound crystallizes in orthorhombic system, space group Pbca, a = 10.9960(10)Angstrom, b = 14.9460(9)Angstrom, c = 27.565(5)Angstrom and Z = 2. According to X-ray crystallographic studies, the diazepine ring is observed to be in a disordered state. The site-occupancy of the major compenent refined to 0.53(1). The C=Se bond length of 1.862(4)Angstrom is a double bond character. The dihedral angle between the two phenyl rings is 37.7(2)degrees.