trans-diaquabis(nicotinamide-N '-)bis(4-nitrobenzoato-O)cobalt(II)


Hokelek T., NECEFOGLU H.

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, vol.54, pp.1242-1244, 1998 (Peer-Reviewed Journal) identifier identifier

  • Publication Type: Article / Article
  • Volume: 54
  • Publication Date: 1998
  • Doi Number: 10.1107/s0108270198004533
  • Journal Name: ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
  • Journal Indexes: Science Citation Index Expanded, Scopus
  • Page Numbers: pp.1242-1244

Abstract

The title cobalt complex, [Co(C7H4NO4)(2)(C6H6N2O)(2)(H2O)(2)], is monomeric and centrosymmetric, and contains two water molecules, two 4-nitrobenzoate and two nicotinamide (NA) ligands, all acting as monodentate ligands. The four nearest O atoms around the Co atom form a slightly distorted square-planar arrangement, with a distorted octahedral coordination completed by the pyridine N atoms of the NA ligand, at a distance of 2.134 (2) Angstrom. The water molecules are hydrogen bonded to the carboxyl O atoms [O ... O 2.634(5) Angstrom].