2-Hydroxyimino-1-phenylethanone thiosemicarbazone monohydrate


Sarikavakli N., Babahan I., ŞAHİN E., HÖKELEK T.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.64, 2008 (SCI İndekslerine Giren Dergi) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 64
  • Basım Tarihi: 2008
  • Doi Numarası: 10.1107/s1600536808004947
  • Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS

Özet

In the title thiosemicarbazone derivative, C9H10N4OS center dot H2O, intramolecular N-H center dot center dot center dot N hydrogen bonds result in the formation of two nearly coplanar five- and six-membered rings, which are also almost coplanar with the adjacent phenyl ring. The oxime group has an E configuration and is involved in intermolecular O-H center dot center dot center dot O hydrogen bonding as a donor. In the crystal structure, intramolecular O-H center dot center dot center dot S and N-H center dot center dot center dot N and intermolecular O-H center dot center dot center dot O and N-H center dot center dot center dot S hydrogen bonds generate edge-fused R-2(2)(8) and R-4(1)(11) ring motifs. The hydrogen-bonded motifs are linked to each other to form a three-dimensional supramolecular network.