Langmuir monolayers with some vic-dioxime ligands and their complexation behaviour

Kesimli, B; Topacli, A; Topacli, C; Gumus, G; Gurol, I; Ahsen, V

doi:10.1016/j.colsurfa.2005.01.007

Langmuir monolayers with some vic-dioxime ligands and their complexation behaviour

Atıf İçin Kopyala

Kesimli B., Topacli A., Topacli C., Gumus G., Gurol I., Ahsen V.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, cilt.256, ss.137-143, 2005 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 256
Basım Tarihi: 2005
Doi Numarası: 10.1016/j.colsurfa.2005.01.007
Dergi Adı: COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.137-143
Hacettepe Üniversitesi Adresli: Hayır

Özet

In this work, the formation of Langmuir monolayers of 12,13-bis(hydroxyimino)-11,14-diazatetracosane (DTC), 14,15-bis(hydroxyimino)13,16-dithiaoctacosane (DOC) and 14,15-bis(hydroxyimino)-13-thiaoctacosane (TOC) molecules at the air-water interface, surface pressure-area (pi-A) isotherm and stability of these monolayers were investigated as a function of pH of subphase. We also studied the monolayer properties of these ligands spread on a subphase containing different metal ions. It is showed that the metal ion concentration, complexation time and counter ions play important roles for the complexation behaviour of these ligands. The optimal conditions for the formation of stable, metal complex containing monolayers and transfer as their Langmuir-Blodgett (LB) films were determined. (c) 2005 Elsevier B.V. All rights reserved.