Trans-diaquabis(N,N-diethylnicotinamide-N-1)bis(4-nitrobenzoato-O)copper(II)


Hokelek T., BUDAK K., NECEFOGLU H.

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, cilt.53, ss.1049-1051, 1997 (SCI-Expanded) identifier identifier

Özet

The title molecule is a crystallographically centrosymmetric mononuclear complex containing two water molecules, two 4-nitrobenzoato and two diethylnicotinamide ligands, [Cu(C7H4NO4)(2)(C10H14N2O)(2)(H2O)(2)], all acting as monodentate ligands. The N and O atoms around the Cu atom form a square-planar arrangement, with the slightly tetragonally distorted octahedral coordination completed by two water O atoms at a distance of 2.485 (2) Angstrom. The water molecules are hydrogen bonded to the carboxyl O atoms [O ... O 2.705(4) Angstrom].