Electrosynthesis of 4,4 '-dinitroazobenzene on PbO2 electrodes

Abaci S., Tamer U., Pekmez K., Yildiz A.

JOURNAL OF APPLIED ELECTROCHEMISTRY, cilt.32, sa.2, ss.193-196, 2002 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 32 Sayı: 2
  • Basım Tarihi: 2002
  • Doi Numarası: 10.1023/a:1014721030568
  • Dergi Adı: JOURNAL OF APPLIED ELECTROCHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.193-196
  • Hacettepe Üniversitesi Adresli: Evet

Özet

Parameters which affect the electrosynthesis of 4,4'-dinitroazobenzene from p-nitroaniline on platinum and PbO2 electrodes were investigated and optimum conditions were determined. Maximum conversion efficiency for electrosynthesis was 95% with a pure beta-PbO2 electrode. It was found that the electrocatalytic activity of a PbO2 electrode depends upon its alpha/beta ratio and its degree of crystallinity. The effects of the added base and water on the conversion efficiency were also elucidated.