Removal of cationic dyes by poly(acrylamide-co-acrylic acid) hydrogels in aqueous solutions


ŞOLPAN ÖZBAY D. , Duran S., TORUN M.

RADIATION PHYSICS AND CHEMISTRY, cilt.77, sa.4, ss.447-452, 2008 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 77 Konu: 4
  • Basım Tarihi: 2008
  • Doi Numarası: 10.1016/j.radphyschem.2007.08.006
  • Dergi Adı: RADIATION PHYSICS AND CHEMISTRY
  • Sayfa Sayıları: ss.447-452

Özet

Poly(acrylamide-co-acrylic acid (poly(AAm-co-AAc)) hydrogels prepared by irradiating with T-radiation were used in experiments on swelling, diffusion, and uptake of some cationic dyes such as Safranine-O (SO) and Magenta (M). Poly(AAm-co-AAc) hydrogels irradiated at 8.0 kGy have been used for swelling and diffusion studies in water and cationic dye solutions. The maximum swellings in water, and SO, and M solutions observed are 2700%, 3500%, and 4000%, respectively. Diffusions of water and cationic dyes within hydrogels have been found to be non-Fickian in character. Adsorption of the cationic dyes onto poly(AAm-co-AAc) hydrogels is studied by the batch adsorption technique. The adsorption type was found Langmuir type in the Giles classification system. The moles of adsorbed dye for SO and M per repeating unit in hydrogel (binding ratio, r) have been calculated as 3834 x 10(-6) and 1323 x 10(-6), respectively. These results show that poly(AAm-co-AAc) hydrogels can be used as adsorbent for water pollutants such as cationic dyes. (C) 2007 Elsevier Ltd. All rights reserved.