An infrared spectroscopic study of pyrazine- and 4,4 '-bipyridyl-T-d-type clathrates: Mn (pyrazine) M(CN)(4) benzene (M = Cd or Hg) and Mn (4,4 '-bipyridyl) M(CN)(4). benzene (M = Zn, Cd or Hg)
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, cilt.39, ss.115-121, 2001 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 39
- Basım Tarihi: 2001
- Doi Numarası: 10.1023/a:1008127407158
- Dergi Adı: JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.115-121
- Hacettepe Üniversitesi Adresli: Evet
Özet
The infrared spectra of the title compounds have been reported. The spectral data suggest that the host framework of these compounds are similar to those of the en-T-d-type clathrate compounds. There is good evidence for hydrogen bonding from ligand molecules to benzene molecules as a pi to sigma hydrogen bond.