Urethanes synthesis from oxamic acids under electrochemical conditions

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Ogbu I. M., Lusseau J., Kurtay G., Robert F., Landais Y.

Chemical Communications, cilt.56, sa.81, ss.12226-12229, 2020 (SCI-Expanded, Scopus)

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 56 Sayı: 81
  • Basım Tarihi: 2020
  • Doi Numarası: 10.1039/d0cc05069e
  • Dergi Adı: Chemical Communications
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chimica, Communication Abstracts, EMBASE, MEDLINE, DIALNET
  • Sayfa Sayıları: ss.12226-12229
  • Açık Arşiv Koleksiyonu: AVESİS Açık Erişim Koleksiyonu
  • Hacettepe Üniversitesi Adresli: Hayır

Özet

© The Royal Society of Chemistry.Urethane synthesis via oxidative decarboxylation of oxamic acids under mild electrochemical conditions is reported. This simple phosgene-free route to urethanes involves an in situ generation of isocyanates by anodic oxidation of oxamic acids in an alcoholic medium. The reaction is applicable to a wide range of oxamic acids, including chiral ones, and alcohols furnishing the desired urethanes in a one-pot process without the use of a chemical oxidant.