N-[bis(2,4,6-trimethylphenoxy)phos-phinoyl]-P,P,P-tris(2,4,6-trimethyl-phenoxy)phosphazene

Hoekelek T., Akduran N., Begec S., Kilic A., Kilic Z.

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, cilt.56, ss.1404-1406, 2000 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 56
  • Basım Tarihi: 2000
  • Doi Numarası: 10.1107/s010827010001177x
  • Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chimica, Compendex, EMBASE, INSPEC, MEDLINE
  • Sayfa Sayıları: ss.1404-1406
  • Hacettepe Üniversitesi Adresli: Hayır

Özet

The title compound, C45H55NO6P2, consists of an acyclic P=N-P(O) monophosphazene chain and five bulky 2,4,6-trimethylphenoxy side groups which predominantly determine the molecular shape. Although the P-N single [1.586 (3) Angstrom] and P=N double [1.517 (3) Angstrom] bonds are significantly different from each other, both are substantially shorter than the ideal P-N single bond. The P-N-P angle [146.0 (2)degrees] corresponds to the upper limit reported for acyclic phosphazene derivatives in the literature.